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- 第 季第 1 集1 - Pilot2007年9月23日43 分鐘When computer geek Chuck Bartowski (series star ZACHARY LEVI) opens an e-mail subliminally encoded with government secrets, he unwittingly downloads an entire server of sensitive data…加入 Prime
- 第 季第 1 集2 - Chuck Versus the Helicopter2007年9月30日43 分鐘As Chuck continues to come to grips with his new life as a spy, tension builds between his recently appointed partners, Sarah and Casey.加入 Prime
- 第 季第 1 集3 - Chuck Versus the Tango2007年10月7日43 分鐘Chuck is finding out that living two separate lives is not going to be easy.加入 Prime
- 第 季第 1 集4 - Chuck Versus the Wookiee2007年10月14日43 分鐘Chuck takes on an unusual task when Sarah's hot colleague from the CIA requests help with a mission.加入 Prime
- 第 季第 1 集5 - Chuck Versus the Sizzling Shrimp2007年10月21日43 分鐘Chuck faces his first moral dilemma as a spy. When agents Sarah and Casey refuse to aid an unauthorized mission by a top Chinese spy taking place in Chinatown, Chuck faces the tough decision to either go against the U.S. government and his friends or do what he believes is right.加入 Prime
- 第 季第 1 集6 - Chuck Versus the Sandworm2007年10月28日41 分鐘When Chuck meets a fellow government agent with a double life, a gadget whiz whose brain makes him a national security asset and a dangerous liability -- much like Chuck -- he must decide whether to turn the agent in to Sarah and Casey or help him escape.加入 Prime
- 第 季第 1 集7 - Chuck Versus the Alma Mater2007年11月4日42 分鐘When Chuck finds out that his former professor is a government operative who is being hunted because of a sensitive top-secret file, he returns to Stanford University, the institution from which he was expelled.加入 Prime
- 第 季第 1 集8 - Chuck Versus the Truth2007年11月11日43 分鐘Chuck battles with his real love life and "cover" love life when he meets a very pretty girl named Lou (recurring guest star RACHEL BILSON), who seems interested in the real Chuck.加入 Prime
- 第 季第 1 集9 - Chuck Versus the Imported Hard Salami2007年11月18日43 分鐘When Chuck starts dating Lou (recurring guest star RACHEL BILSON), a sandwich maker, and things seem to be going really well, the situation incites some jealousy from Chuck's "ex-girlfriend" Sarah, who discovers that her feelings may not have been just part a cover story.加入 Prime
- 第 季第 1 集10 - Chuck Versus the Nemesis2007年11月25日43 分鐘At Thanksgiving, Bryce (recurring guest star MATTHEW BOMER) returns, after being assumed dead.加入 Prime
- 第 季第 1 集11 - Chuck Versus the Crown Vic2007年12月2日42 分鐘Still licking his wounds after realizing Sarah still has feelings for Bryce (recurring guest star MATTHEW BOMER - "Traveler"), Chuck must assume the cover of being Sarah’s husband on a mission to foil a politically connected counterfeiter and yachtsman.加入 Prime
- 第 季第 1 集12 - Chuck Versus the Undercover Lover2008年1月23日43 分鐘Chuck discovers that several Russian arms dealers are secretly meeting in Los Angeles.加入 Prime
- 第 季第 1 集13 - Chuck Versus the Marlin2008年1月23日42 分鐘Captain Awesome (recurring guest star RYAN McPARTLIN) asks Chuck if he can have Ellie's hand in marriage, and then insists that Chuck hold on to the ring until the proposal is planned.加入 Prime
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